Aquabis(4-nitrobenzoato)-κ2 O,O′;κO-(piperidinium-4-carboxylato-κ2 O,O′)cadmium(II)
نویسندگان
چکیده
In the mixed ligand title compound, [Cd(C(6)H(11)NO(2))(C(7)H(4)NO(4))(2)(H(2)O)], which exhibits a discrete mononuclear structure, the Cd(II )atom is in a distorted octa-hedral geometry, surrounded by five carboxyl-ate O atoms and one coordinated water mol-ecule. The piperdinium ring adopts a chair conformation and the two 4-nitro-benzoate rings are oriented at a dihedral angle of 75.8 (1)°. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds link the mononuclear entities into a three-dimensional supra-molecular network.
منابع مشابه
Aqua(furan-2-carboxylato-κO)(furan-2-carboxylato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)copper(II) methanol hemisolvate
The asymmetric unit of the title compound, [Cu(C(5)H(3)O(3))(2)(C(12)H(8)N(2))(2)(H(2)O)]·0.5CH(3)OH, contains two Cu(II) complex mol-ecules and one methanol solvent mol-ecule with the metal centres in strongly distorted octahedral coordination. The coordinated water mol-ecule is involved in inter-molecular O-H⋯O hydrogen bonding, which links the complex mol-ecules into chains propagating along...
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